Organometallic macrocyclic chemistry. 6. Chelate-assisted macrocyclization of 4,7,10-trithiatrideca-2,11-diyne

Hill, Anthony; Rae, A David; Schultz, Madeleine; Willis, Anthony

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Organometallic macrocyclic chemistry. 6. Chelate-assisted macrocyclization of 4,7,10-trithiatrideca-2,11-diyne

Date

2004

Authors

Hill, Anthony

Rae, A David

Schultz, Madeleine

Willis, Anthony

Publisher

American Chemical Society

Abstract

The diyne 4,7,10-trithiatrideca-2,11-diyne (TTDD) reacts smoothly at room temperature with [Ru(CO)2(PPh3)3] to form [Ru(CO)(PPh3) {η4-S(C2H4SCCMe)2CO-κS}], a cyclopentadienone complex in which the unique sulfur atom is also coordinated to the metal but