Facile C-H bond activation: synthesis of the N 4 C donor set pentadentate ligand 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) and a structural study of its alkyl?cobalt(III) complex [Co(dmpdacn- C )(OH 2 )](ClO 4 ) 2 ⋅H 2 O and its hydroxylated derivative [Co(dmpdacnOH- O )Cl](ClO 4 ) 2 ⋅C 3 H 6 O

Simple item page
dc.contributor.authorZhou, Xiangting
dc.contributor.authorDay, Anthony
dc.contributor.authorEdwards, Alison
dc.contributor.authorWillis, Anthony
dc.contributor.authorJackson, William Gregory
dc.date.accessioned2015-12-13T22:55:16Z
dc.date.issued2005
dc.date.updated2015-12-11T11:09:25Z
dc.description.abstractThe 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) ligand with a N4C donor set deprotonates at a CH2 γ to an amine under extraordinarily mild conditions (pH 7) and binds as a pentadentate ligand to Co(III) as the [Co(dmpdacn-C)(OH2)]2+ complex.
dc.identifier.issn0020-1669
dc.identifier.urihttp://hdl.handle.net/1885/82456
dc.publisherAmerican Chemical Society
dc.sourceInorganic Chemistry
dc.subjectKeywords: 1,4 bis(2 pyridylmethyl) 1,4 diazacyclononane; amine; chloride; cobalt complex; ligand; pyridine derivative; unclassified drug; article; chemical bond; drug hydroxylation; hydrolysis kinetics; nuclear magnetic resonance; oxidation; synthesis; X ray crysta
dc.titleFacile C-H bond activation: synthesis of the N 4 C donor set pentadentate ligand 1,4-bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) and a structural study of its alkyl?cobalt(III) complex [Co(dmpdacn- C )(OH 2 )](ClO 4 ) 2 ⋅H 2 O and its hydroxylated derivative [Co(dmpdacnOH- O )Cl](ClO 4 ) 2 ⋅C 3 H 6 O
dc.typeJournal article
local.bibliographicCitation.issue2
local.bibliographicCitation.lastpage460
local.bibliographicCitation.startpage452
local.contributor.affiliationZhou, Xiangting, University of New South Wales
local.contributor.affiliationDay, Anthony, University of New South Wales
local.contributor.affiliationEdwards, Alison, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationJackson, William Gregory, University of New South Wales, ADFA
local.contributor.authoremailu8512028@anu.edu.au
local.contributor.authoruidEdwards, Alison, u9900186
local.contributor.authoruidWillis, Anthony, u8512028
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor030606 - Structural Chemistry and Spectroscopy
local.identifier.ariespublicationMigratedxPub10707
local.identifier.citationvolume44
local.identifier.doi10.1021/ic040081q
local.identifier.scopusID2-s2.0-12344272889
local.identifier.uidSubmittedByMigrated
local.type.statusPublished Version

Downloads

Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
01_Zhou_Facile_C-H_bond_activation:_2005.pdf
Size:
270.09 KB
Format:
Adobe Portable Document Format
Download

Collections

ANU Research Publications

DSpace software copyright © 2002-2024 LYRASIS