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Co-polymerization analysis of thermosetting resins using 1 H- 15 N- 13 C triple resonance NMR spectroscopy

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dc.contributor.authorPhilbrook, Amy
dc.contributor.authorEarnshaw, Scott
dc.contributor.authorEaston, Christopher
dc.contributor.authorKeniry, Max
dc.contributor.authorLatter, Melissa
dc.date.accessioned2015-12-10T23:02:01Z
dc.date.issued2013
dc.date.updated2016-02-24T10:25:27Z
dc.description.abstract1H-15N-13C correlation NMR spectroscopy techniques developed to identify and characterize co-polymer fragments in melamine-urea-formaldehyde (MUF) and phenol-urea-formaldehyde (PUF) model systems have been applied to industrially prepared MUF, PUF, and phenol-melamine-formaldehyde (PMF) resins. The NMR data confirm that co-polymers form in a commercially prepared MUF resin manufactured by Momentive Specialty Chemicals Pty. Ltd. Spectra from PUF model reactions were compared with those from a PUF resin and it was determined that PUF co-polymers did not form in the resin prepared using typical temperature and pH. Finally, NMR spectroscopy was used to identify and characterize PMF co-polymer bonds in a phenol-melamine- urea-formaldehyde (PMUF) resin prepared using a procedure from Momentive Specialty Chemicals Pty. Ltd. With these NMR techniques in hand, it is now possible to relate co-polymer structures to properties of commercial thermosets.
dc.identifier.issn0021-8995
dc.identifier.urihttp://hdl.handle.net/1885/61831
dc.publisherJohn Wiley & Sons Inc
dc.sourceJournal of Applied Polymer Science
dc.subjectKeywords: Model reactions; Model system; MUF resins; NMR techniques; Phenol urea formaldehydes; Specialty chemicals; Triple resonance; Urea formaldehyde; Adhesives; Copolymers; Nuclear magnetic resonance spectroscopy; Phenols; Polymers; Resins; Spectroscopy; Thermo adhesives; copolymers; resins; spectroscopy; thermosets
dc.titleCo-polymerization analysis of thermosetting resins using 1 H- 15 N- 13 C triple resonance NMR spectroscopy
dc.typeJournal article
local.bibliographicCitation.issue5
local.bibliographicCitation.lastpage3381
local.bibliographicCitation.startpage3375
local.contributor.affiliationPhilbrook, Amy, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationEarnshaw, Scott, Momentive Specialty Chemicals Pty Ltd
local.contributor.affiliationEaston, Christopher, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationKeniry, Max, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLatter, Melissa, College of Physical and Mathematical Sciences, ANU
local.contributor.authoremailu9500570@anu.edu.au
local.contributor.authoruidPhilbrook, Amy, u4037572
local.contributor.authoruidEaston, Christopher, u9500570
local.contributor.authoruidKeniry, Max, u8800397
local.contributor.authoruidLatter, Melissa, u5090941
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030305 - Polymerisation Mechanisms
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu4005981xPUB643
local.identifier.citationvolume128
local.identifier.doi10.1002/app.38516
local.identifier.scopusID2-s2.0-84874938915
local.identifier.thomsonID000315910500097
local.identifier.uidSubmittedByu4005981
local.type.statusPublished Version

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