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The mechanism of Bu 3 SnH-mediated homolytic aromatic substitution

Date

Authors

Beckwith, Athelstan (Athel)

Bowry, Vincent W

Bowman, W Russell

Mann, Emma

Parr, Jonathan

Storey, John W

Publisher

Wiley-VCH Verlag GMBH

Abstract

The fate of intermediate π radicals is crucial in Bu 3SnH-mediated cyclization by homolytic aromatic substitution, for example, of bromo compound 1 via radical 2 to give oxindole 3 (AIBN = azobisisobutyronitrile). The results indicate that the mechanism

Keywords

Keywords: Radical reactions; Bromine compounds; Free radicals; Hydrogen; Solvents; Substitution reactions; Aromatic compounds; aromatic compound; azobisisobutyronitrile; hydrogen; oxindole; polycyclic aromatic hydrocarbon; radical; solvent; tin; unclassified drug; Azo compounds; Cyclization; Radical reactions; Radicals; Reaction mechanisms

URI

http://hdl.handle.net/1885/86208

Collections

ANU Research Publications

Source

Angewandte Chemie International Edition

Type

Journal article

DOI

10.1002/anie.200352419

Restricted until

2037-12-31

Downloads

File

Description

01_Beckwith_The_mechanism_of_Bu_3_2004.pdf (108.66 KB)

02_Beckwith_The_mechanism_of_Bu_3_2004.pdf (107.73 KB)

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