Electronic Spectrum of Dicyanoacetylene. 2. Interpretation of the 2800 Å Transition
Date
2003
Authors
Fischer, Gad
Johnson, G Dana
Ramsay, D A
Ross, I
Journal Title
Journal ISSN
Volume Title
Publisher
American Chemical Society
Abstract
The 2800 Å forbidden1Σu- ←1Σg+ transition of dicyanoacetylene shows conventional vibronic origins due to the two πg vibrations and a third involving the lower πu vibration. For the latter we argue against a magnetic dipole mechanism and propose tha
Description
Keywords
Keywords: Absorption spectroscopy; Electron energy levels; Magnetic properties; Molecular structure; Molecular vibrations; Organic compounds; Quantum theory; Dicyanoacetylene; Electronic spectrum; Magnetic dipole; Quantum numbers; Electron transitions
Citation
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Source
Journal of Physical Chemistry A
Type
Journal article