Effect of temperature and solvent on polymer tacticity in the free-radical polymerization of styrene and methyl methacrylate
Date
2013
Authors
Smith, Leesa
Coote, Michelle
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Publisher
Wiley-VCH Verlag GMBH
Abstract
The effect of temperature and solvent on polymer tacticity in free-radical polymerization of styrene and methyl methacrylate was studied by 13C and 1H NMR, respectively. Polystyrene shows a mild syndiotactic tendency (Pm = 0.36 ± 0.02) that is independen
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Keywords
Keywords: Effect of temperature; Methyl methacrylates; Polymer tacticity; Polymerization solvents; Propagation reaction; Solvent effects; Syndiotactics; Tacticities; Acetone; Acrylic monomers; Esters; Free radical polymerization; Organic solvents; Polystyrenes; Sol poly(methyl methacrylate); polystyrene; radical polymerization; solvent effects; syndiotactic; tacticity
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Source
Journal of Polymer Science: Part A: Polymer Chemistry
Type
Journal article
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Restricted until
2037-12-31
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