N-Heterocyclic Silyl Pincer Ligands
Date
2014
Authors
Dixon, Lily
Hill, Anthony
Sinha, Arup
Ward, James
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American Chemical Society
Abstract
The reaction of 1,2-C6H4(NHCH2PPh 2)2 with chlorosilanes Cl2SiHR (R = Ph, Cl) affords the benzosiladiazoles RHSi(NCH2PPh2) 2C6H4 (R = Ph, 1; Cl, 2). The phenyl derivative 1 undergoes chelate-assisted Si-H activation with [RuPhCl(CO)(PPh 3)2] and [RhCl(PPh
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Organometallics
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Journal article
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2037-12-31
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