Arsenicin A, A Natural Polyarsenical: Synthesis and Crystal Structure
Date
2010
Authors
Lu, Di
Rae, A David
Salem, Geoffrey
Weir, Michelle
Willis, Anthony
Wild, Stanley (Bruce)
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Volume Title
Publisher
American Chemical Society
Abstract
The synthesis of the natural polyarsenical Arsenicin A and its crystal structure are described. The molecule has the adamantane-type structure of arsenic trioxide in which three of the oxygen atoms have been replaced by methylene groups to generate four arsenic stereocenters of the same configuration in each enantiomer of the racemate.
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Keywords
Keywords: Adamantanes; Arsenic trioxide; Methylene groups; Oxygen atom; Stereocenters; Synthesis and crystal structure; Type structures; Arsenic; Oxygen; Crystal atomic structure
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Organometallics
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Journal article
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2037-12-31
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