Synthetic and Computational Studies of Thiocarbonyl/σ-Organyl Coupling Reactions

Green, Jennifer C; Hector, Andrew L; Hill, Anthony; Lin, Sibo; Wilton-Ely, James D. E. T.

Synthetic and Computational Studies of Thiocarbonyl/σ-Organyl Coupling Reactions

Date

2008

Authors

Green, Jennifer C

Hector, Andrew L

Hill, Anthony

Lin, Sibo

Wilton-Ely, James D. E. T.

Publisher

American Chemical Society

Abstract

The reactions of a range of coordinatively unsaturated σ-organyl thiocarbonyl complexes with 1,4,7-trithiacyclononane ([9]aneS3) have been investigated, leading in some but not all cases to migratory insertive coupling of thiocarbonyl and σ-organyl liga