Di(Carbido)Tetracosa(Carbonyl)-Decaruthenate(2-) Salts
Date
2014
Authors
Bruce, Michael
Castro, Aurora
Humphrey, Paul A
Maitlis, Peter
Zaitseva, Natahsa N.
Viau, Lydie
Humphrey, Mark
Journal Title
Journal ISSN
Volume Title
Publisher
John Wiley & Sons Inc
Abstract
For the metal ruthenium, many examples of clusters with different nuclearity are known. The Ru10C2 cluster is formed by edge sharing of two Ru6C clusters. This chapter describes a synthesis of the decanuclear anion [Ru10C2(CO)24]2- from Ru3(CO)12 and calcium carbide in up to 50% yield. The chapter discusses the procedures and properties of calcium di(carbido)tetracosa(carbonyl) decaruthenium(2-) and BIS(triphenylphosphoranylidene)ammonium di (carbido)tetracosa(carbonyl)decaruthenium(2-).
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Keywords
Citation
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Source
Type
Book chapter
Book Title
Inorganic Syntheses, Vol. 36
Entity type
Access Statement
License Rights
DOI
10.1002/9781118744994.ch23
Restricted until
2037-12-31